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Silver(II) and Silver(III) Intermediates in Alkene Aziridination with a Dinuclear Silver(I) Nitrene Transfer Catalyst

https://doi.org/10.1021/acscatal.0c00065

Elkoush, Tasneem; Mak, Choi L.; Paley, Daniel W.; Campbell, Michael G. (April 2020, ACS Catalysis)

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Visible Light Absorption and Long-Lived Excited States in Dinuclear Silver(I) Complexes with Redox-Active Ligands

https://doi.org/10.1021/acs.inorgchem.0c02938

Shields, Dylan J.; Elkoush, Tasneem; Miura-Stempel, Emily; Mak, Choi L.; Niu, Guang-Hao; Gudmundsdottir, Anna D.; Campbell, Michael G. (December 2020, Inorganic Chemistry)
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Dinuclear Silver Complexes in Catalysis

https://doi.org/10.1002/anie.202106937

Elkoush, Tasneem; Reich, Natasha D.; Campbell, Michael G. (July 2021, Angewandte Chemie International Edition)

Abstract Over the past two decades, there has been a substantial increase in the number of synthetically useful transformations catalyzed by silver. Across the range of silver‐catalyzed reactions that have been reported, dinuclear species often emerge as a common feature, either as the (pre‐)catalysts themselves or as intermediates during catalysis. This Minireview explores the role of dinuclear silver complexes in homogeneous catalysis, which we hope will aid in the development of improved design principles for silver catalysts.
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